Email this article Evolutionary process and mechanical properties of polymers: A comprehensive review
DOI: https://doi.org/10.20528/cjcrl.2025.04.005
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The growing demand for innovative construction materials has driven the exploration of polymer-based composites due to their enhanced mechanical performance and potential environmental benefits. However, a clear understanding of the historical development, classification, and structural behavior of polymers in construction remains limited. This review aims to bridge this gap by synthesizing current knowledge on the historical evolution, mechanical benefits, chemical benefits, drawbacks and real world applications of polymers in construction. The study focuses on key thermosetting resins such as polyester, epoxy, vinyl ester, and PET and assesses their mechanical properties relevant to structural applications. To address the lack of integrated insight in the literature, the review compiles and compares data from various primary sources. Mechanical properties such as tensile, compressive, and flexural strength are evaluated to determine the suitability of each polymer for construction use. The outcomes indicate that epoxy resins demonstrate superior tensile and flexural strength, while polyester and polyethylene terephthalate PET offer notable advantages in compressive resistance and sustainability. Overall, the findings provide a consolidated understanding of polymer development and performance, offering valuable guidance for researchers and engineers aiming to enhance material efficiency, durability, and environmental responsibility in the construction industry.
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Akarken G, Cengiz U, Ozturk N, Balkaner C (2025). Self-cleaning superhydrophobic polyester resin production for gel coat applications. Progress in Organic Coatings, 198, 108884.
Alami AH, Ghani Olabi A, Alashkar A, Alasad S, Aljaghoub H, Rezk H, Abdelkareem MA (2023). Additive manufacturing in the aerospace and automotive industries: Recent trends and role in achieving sustainable development goals. Ain Shams Engineering Journal, 14(11), 102516.
Alhazmi H, Shah SAR, Anwar MK, Raza A, Ullah MK, Iqbal F (2021). Utilization of polymer concrete composites for a circular economy: A comparative review for assessment of recycling and waste utilization. Polymers, 13(13), 2135.
Ali A, Ansari AA (2013). Polymer concrete as innovative material for development of sustainable architecture. 2nd International Conference on Emerging Trends in Engineering & Technology, Teerthanker Mahaveer University, Moradabad, India.
Aravecchia N, Bañuls-Ciscar J, Caverzan A, Ceccone G, Cuenca E, Ferrara L, Grigoriadis K, Negro P, Rodriquens M (2023). On the feasibility of using Polyester (PE) waste particles from metal coating industry as a secondary raw materials in concrete. Cleaner Materials, 9, 100193.
Azhdarpour AM, Nikoudel MR, Taheri M (2016). The effect of using polyethylene terephthalate particles on physical and strength-related properties of concrete; a laboratory evaluation. Construction and Building Materials, 109, 55–62.
Batista WGS, Costa BLS, Aum PTP, Oliveira YH, Freitas JCO (2021). Evaluation of reused polyester resin from PET bottles for application as a potential barrier material. Journal of Petroleum Science and Engineering, 205, 108776.
Bedi R, Chandra R, Singh SP (2013). Mechanical properties of polymer concrete. Journal of Composites, 2013(8), 1–12.
Benmokrane B, Ali AH, Mohamed HM, ElSafty A, Manalo A (2017). Laboratory assessment and durability performance of vinyl-ester, polyester, and epoxy glass-FRP bars for concrete structures. Composites Part B: Engineering, 114, 163–174.
Bulut HA, Şahin R (2017). A study on mechanical properties of polymer concrete containing electronic plastic waste. Composite Structures, 178, 50–62.
Byron D, Pacheli Heitman A, Neves J, de Souza PP, de Oliveira Patricio PS (2021). Evaluation of properties of polymer concrete based on epoxy resin and functionalized carbon nanotubes. Construction and Building Materials, 309, 125155.
Choe YA, Pak RB, Kim Sil, Ju KS (2023). Preparation and characterization of water-reducible polyester resin based on waste PET for insulation varnish. RSC Advances, 13(49), 34637–34645.
Fame CM, Ueda T, Ntjam Minkeng MA, Wu C (2024). Durability of epoxy and vinyl ester polymers in wet, seawater, and seawater sea sand concrete environments: Molecular dynamics simulations. Construction and Building Materials, 451, 138645.
Fei M, Luo C, Zheng X, Fu T, Ling K, Chen H, Liu W, Qiu R (2024). High-performance pervious concrete using cost-effective modified vinyl ester as binder. Construction and Building Materials, 414, 134908.
Feldman D (2008). Polymer history. Designed Monomers and Polymers, 11, 1–15.
Fowler DW (1999). Polymers in concrete: a vision for the 21st century. Cement and Concrete Composites, 21(5–6), 449–452.
Godara SS, Yadav A, Goswami B, Rana RS (2021). Review on history and characterization of polymer composite materials. Materials Today: Proceedings, 44(Part 1), 2674–2677.
Grigoriadis K, Bañuls-Ciscar J, Caverzan A, Negro P, Senaldi C, Ceccone G (2023). Use of irradiated PET plastic waste for partially replacing cement in concrete? Waste Management, 170, 193–203.
Gulabbhai DP, Kruger D, Hira MK (2025). Testing the performance of vinyl ester and polyester polymer concrete following exposure to artificially induced climatic environments. Springer Proceedings in Materials, 61, 539–546.
Heidari-Rarani M, Asdollah-Tabar M, Mirkhalaf M (2023). Experimental investigation and micromechanics-based damage modeling of tensile failure of polymer concrete reinforced with recycled PET bottles. Engineering Failure Analysis, 148, 107197.
Khallouqi A, Halimi A, El rhazouani O (2024). Evaluating polyester resin as a viable substitute for PMMA in computed tomography dosimetry phantoms. Nuclear Engineering and Technology, 56(9), 3758–3763.
Koirala S, Hirachan B, Chhetri SG, Gyawali TR (2025). Utilizing residual waste particles from polyethylene terephthalate (PET) waste pellet production in cement mortar. International Journal of Sustainable Engineering, 18(1), 1–13.
Kumar R (2016). A review on epoxy and polyester based polymer concrete and exploration of polyfurfuryl alcohol as polymer concrete. Journal of Polymers, 2016, 1–13.
Luo T, Zhao Y, Fu K, Cui X, Chen B (2024). High-efficiency manufacturing of epoxy resins through two-point initiation of frontal polymerization. Chemical Engineering Journal, 496, 154148.
Martínez-López Á, Martínez-Barrera G, Vigueras-Santiago E, Martínez-López M, Gencel O (2022). Mechanical improvement of polymer concrete by using aged polyester resin, nanosilica and gamma rays. Journal of Building Engineering, 58, 105083.
Mehdar YTH (2024). Investigating the Impact of temperature and storage time on antimony release from polyethylene terephthalate (PET) plastic used for bottled drinking water. Desalination and Water Treatment, 319, 100474.
Nodehi M (2022). Epoxy, polyester and vinyl ester based polymer concrete: a review. Innovative Infrastructure Solutions, 7, 64.
Oladele IO, Onuh LN, Siengchin S, Sanjay MR, Adelani SO (2023). Modern applications of polymer composites in structural industries: a review of philosophies, product development, and graphical applications. Applied Science and Engineering Progress, 17(1), 6884.
Pacheco-Torgal F, Ding Y, Jalali S (2012). Properties and durability of concrete containing polymeric wastes (tyre rubber and polyethylene terephthalate bottles): An overview. Construction and Building Materials, 30, 714–724.
Rayati S, Ghadami A, Ehsani M, Hasanbeik NY, Ghafourihayeasl E, Rahdar A, Fathi-karkan S, Pandey S (2025). Enhanced mechanical and thermal properties of epoxy vinyl ester nanocomposites through hybridization with functionalized graphene oxide and nanoglass flakes. Inorganic Chemistry Communications, 172, 113642.
Rebeiz KS (1996). Precast use of polymer concrete using unsaturated polyester resin based on recycled PET waste. Construction and Building Materials, 10(3), 215–220.
Rochman T, Sumardi Susilo SH, Wardhana HA (2024). Vinyl-ester-based polymer concrete incorporating high volume fly ash under tensile, compressive, and flexural loads. Journal of King Saud University - Engineering Sciences, 36(3), 153–163.
Rubeš D, Vinklárek J, Podzimek Š, Honzíček J (2024). Bio-based unsaturated polyester resin from post-consumer PET. RSC Advances, 14(12), 8536–8547.
Safinia S, Alkalbani A (2016). Use of recycled plastic water bottles in concrete blocks. Procedia Engineering, 164, 214–221.
Salami BA, Bahraq AA, Haq MM ul, Ojelade OA, Taiwo R, Wahab S, Adewumi AA, Ibrahim M (2024). Polymer-enhanced concrete: A comprehensive review of innovations and pathways for resilient and sustainable materials. Next Materials, 4, 100225.
Sarwar S, Molla SR, Das S, Tammim L, Ahmed FF, Akter S (2024). Algal deterioration of PET (polyethylene terephthalate) plastic bottle in combination with physical and chemical pretreatments: A macrocosm study. Environmental and Sustainability Indicators, 21, 100329.
Seewoo BJ, Wong EVS, Mulders YR, Goodes LM, Eroglu E, Brunner M, Gozt A, Toshniwal P, Symeonides C, Dunlop SA (2024). Impacts associated with the plastic polymers polycarbonate, polystyrene, polyvinyl chloride, and polybutadiene across their life cycle: A review. Heliyon, 10(12), e32912.
Silva DA, Betioli AM, Gleize PJP, Roman HR, Gómez LA, Ribeiro JLD (2005). Degradation of recycled PET fibers in Portland cement-based materials. Cement and Concrete Research, 35(9), 1741–1746.
Soni V, Dinh DA, Poonia K, Kumar R, Singh P, Ponnusamy VK, Selvasembian R, Singh A, Chaudhary V, Thakur S, Nguyen LH, Phan Thi LA, Nguyen VH, Raizada P (2024). Upcycling of polyethylene terephthalate (PET) plastic wastes into carbon-based nanomaterials: Current status and future perspectives. In European Polymer Journal, 215, 113249.
Surucu O (2025). Electrochemical analysis of PET microplastics and detection of elements in PET bottles. Microchemical Journal, 208, 112422.
Suyambulingam I, Sahayaraj Arockiasamy F, Divakaran D, Rangappa SM, Siengchin S (2025). Introduction to polymer composites-Historical aspects and building blocks. In: Sustainable Fillers/Plasticizers for Polymer Composites. Woodhead Publishing, Elsevier.
Tabatabaeian M, Khaloo A, Khaloo H (2019). An innovative high performance pervious concrete with polyester and epoxy resins. Construction and Building Materials, 228, 116820.
Thomason J, Xypolias G (2024). Investigation of the effects of scale and cure environment on the properties of vinyl ester polymer. Polymer, 307, 127344.
Tsyklinskaya AM, Polivanovskaia DA, Grammatikova NE, Zhavoronok ES, Birin KP, Senchikhin IN (2024). Biocidal polymer coatings based on porphyrin-modified epoxy-amine networks. Reactive and Functional Polymers, 205, 106099.
Umasabor RI, Daniel SC (2020). The effect of using polyethylene terephthalate as an additive on the flexural and compressive strength of concrete. Heliyon, 6(8), e04700.
van Zyl FW, Kruger D (2025). The use of polymer concrete as a cost-effective and durable alternative for rapid pothole repair in asphalt surfaces. Springer Proceedings in Materials, 61, 374–383.
Venu H, Anand Chairman C, Ravichandran M, Sieh Kiong T, Kannan S, Razali NM, Fouly A (2024). Analysis of mechanical properties of basalt fabric reinforced fly ash filled vinyl ester composites using multi criteria decision making technique. Thermal Science and Engineering Progress, 54, 102869.
Verma C, Olasunkanmi LO, Akpan ED, Quraishi MA, Dagdag O, El Gouri M, Sherif ESM, Ebenso EE (2020). Epoxy resins as anticorrosive polymeric materials: A review. Reactive and Functional Polymers, 156, 104741.
Wang CY, Chu HY, Wang CC (2024). Converting waste PET plastics to high value-added MOFs-based functional materials: A state of the art review. Coordination Chemistry Reviews, 518, 216106.
Wang RM, Zheng SR, Zheng YP (2011). Polymer Matrix Composites and Technology. Woodhead Publishing, Elsevier.
Wang TS, Parng JK, Shau MD (1999). The synthesis and properties of new epoxy resin containing phosphorus and nitrogen groups for flame retardancy. Journal of Applied Polymer Science, 74(2), 413–421.
Wang Z, Phua ZH, Chan WP, Lisak G (2024). Evaluating fresh and hardened properties of mortar composite with different types of modified polyethylene terephthalate (PET) materials as additives: Modification effects, surface properties, shape factors. Chemosphere, 367, 143567.
Wattanavichien P, Iwanami M (2024). Investigation of the mechanical, microstructure, and durability properties of concrete with fine uniform and non-uniform polyethylene terephthalate (PET) aggregates. Cleaner Materials, 13, 100267.
Waysal S, Patil YD, Dholkiya BZ, Bhoi AM (2023). Employing copper slag and pet polymer in self-compacting concrete. Materials Today: Proceedings, 93, 515–521.
Yılmaz Y, Nayır S (2024). Machine learning based prediction of compressive and flexural strength of recycled plastic waste aggregate concrete. Structures, 69, 107363.
Zhang K, Fu P, Wang Y, Chang Q, Yang W, You Z, Huang J, Nie X, Chen J (2024). Tung oil-based modifier strengthening and toughening epoxy resin by sacrificial bond. Industrial Crops and Products, 222, 120116.
